Rinting default situations provided by the software program for high-resolution PLA-based prints: nozzle Xanthoangelol Purity temperature = 220 C, infill = 100 , layer height = 0.ten mm, printing speed = 50 mm/s). Extruded and printed rod-shaped prototypes were coated with (i) an ethanolic answer (final concentration 30 weight/volume) containing EudragitRS and RL (mixed inside a three:1 ratio by weight) and TEC because the plasticizer (15 by weight on the dry polymeric blend) and (ii) a 30 ready-to-use aqueous suspension of EudragitNE. Description of your equipment and coating process created may be the major subject in the manuscript. Coating processes had been carried out at ambient situations (21 0.five C and 55 RH). 2.two.2. Characterization of Prototypes Uncoated and coated prototypes were characterized for weight (n = six; Sartorius, Varedo, Italy) and dimensions. The diameter of your extruded specimens was checked using a caliper in three different positions to rule out any attainable ovalization phenomena. The caliper was also used to measure width and height of FDM prototypes in 3 distinctive points along their length. To evaluate thickness in the coated prototypes, samples (n = six) had been reduce, and photographs of their cross CC-90005 custom synthesis section had been acquired applying a digital microscope (Digital Microscope AM-413T, Dino-Lite, Milan, Italy; resolution = 1.three Megapixel – 1280 1024). The latter have been processed (ImageJ, application version 1.eight.0_172, Milan, Italy) to evaluate the coating thickness in at least 6 unique positions along the circumference of your samples, as highlighted in Figure 1. Uncoated and coated prototypes have been tested for shape memory effect in accordance with . Samples had been heated at 35 C above their glass transition temperature (Tg ) and forced to take on a temporary U-shape. Then, they were cooled under Tg inside the deformed shape. Shape recovery was studied upon immersion from the deformed specimens into a crystallization vessel, filled with 250 mL of HCl 0.1N and kept at 37 0.5 C by means of a thermoregulated bath. The recovery with the original shape was monitored employing a digital camera positioned above (distance 13 cm) the specimens (GoPro Hero Session, Milan, Italy; n = three). The photographs acquired had been processed working with a certain computer software (ImageJ, computer software version 1.8.0_172, Milan, Italy) to calculate the recovery index (RI) as follows. RI = – p – p (1)exactly where p would be the angle obtained inside the programming phase (angles in rad).Coatings 2021, 11, x 1252 PEER Overview Coatings 2021, 11, FOR4 of49ofFigure 1. Digital photograph with the cross-section an extruded rod coated for 16 16 with all the Figure 1. Digital photograph of the cross-section ofof an extruded rod coated for minmin with all the EudragitNE aqueous suspension with thickness measurements taken 7 7 various positions EudragitNE aqueous suspension with thickness measurements taken inin different positions (DL0(DL0 DL6). L6 ).By linear interpolation with the recovery information straight away ahead of and soon after the time point Uncoated and coated prototypes have been tested for shape memory effect in line with of interest, instances to 50 (t50 RI ) and 80 (t80 RI ) recovery, respectively, had been calculated. . Samples had been heated prototypes was determined transition temperature Instruments, Tg of the rod-shaped at 35 above their glass by DSC (DSC Q100, TA (Tg) and forced to take on a temporary n = 1) making use of nitrogen werepurge gas (70 mL/min).deformed shape. New Castle, DE, USA; U-shape. Then, they as a cooled under Tg in the Indium was Shapeas a calibration typical.